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Molecular Imprinted Sensor Including Au Nanoparticles/Polyoxometalate/Two-Dimensional Hexagonal Boron Nitride Nanocomposite for Diazinon Recognition
ECS Journal of Solid State Science and Technology ( IF 2.2 ) Pub Date : 2020-10-13 , DOI: 10.1149/2162-8777/abbe6a
Hilal Medetalibeyoğlu 1 , Murat Beytur 1 , Sevda Manap 1 , Ceren Karaman 2 , Faruk Kardaş 3 , Onur Akyıldırım 4 , Gl Kotan 5 , Haydar Yksek 1 , Necip Atar 6 , Mehmet Ltfi Yola 7
Affiliation  

Diazinon [O,O-diethyl O-(2-isopropyl-6-methylpyrimidin4-yl) thiophosphate] (DIA) is a significant organophosphorus insecticide in agricultural applications. Thus, sensitive analytical methods development is important for a healthy lifestyle. In this work, the electrochemical detection of DIA molecule in fruit juice samples by using gold nanoparticles (AuNPs) incorporated polyoxometalate (POM)/two-dimensional hexagonal boron nitride (2D-hBN) nanosheets and molecularly imprinted polymer (MIP) was reported. To characterize as-prepared nanomaterials scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and energy dispersive X-ray analysis (EDX) techniques were performed. The electrochemical behavior of the electrodes was examined by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). The as-fabricated DIA imprinted electrode displayed a ...

中文翻译:

分子印迹传感器,包括金纳米颗粒/多金属氧酸盐/二维六方氮化硼纳米复合材料用于二嗪农识别

二嗪农[O,O-二乙基O-(2-异丙基-6-甲基嘧啶4-基)硫代磷酸酯](DIA)在农业应用中是一种重要的有机磷杀虫剂。因此,开发灵敏的分析方法对于健康的生活方式至关重要。在这项工作中,报告了通过使用掺有多金属氧酸盐(POM)/二维六方氮化硼(2D-hBN)纳米片和分子印迹聚合物(MIP)的金纳米颗粒(AuNPs)电化学检测果汁样品中的DIA分子。为了表征制备的纳米材料,进行了扫描电子显微镜(SEM),透射电子显微镜(TEM),X射线衍射(XRD),X射线光电子能谱(XPS)和能量色散X射线分析(EDX)技术。通过循环伏安法(CV)检查电极的电化学行为,电化学阻抗谱(EIS)和差分脉冲伏安法(DPV)。制成的DIA压印电极显示...
更新日期:2020-10-14
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