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More is better: aggregation induced luminescence and exceptional chirality and circularly polarized luminescence of chiral gold clusters
Materials Chemistry Frontiers ( IF 7 ) Pub Date : 2020-10-10 , DOI: 10.1039/d0qm00552e
Xiao-Yan Wang 1, 2, 3 , Jing Zhang 1, 2, 3, 4, 5 , Jun Yin 1, 2, 3 , Sheng Hua Liu 1, 2, 3 , Ben Zhong Tang 4, 5, 6, 7, 8
Affiliation  

The influence of the aggregation-induced emission (AIE) effect on the luminescence and the chirality of two chiral Au clusters (R)-1 and (S)-1 was well demonstrated. Their solid states exhibited extremely bright phosphorescence with quantum yields above 70%. The two clusters were free of luminescence and chirality in diluted solution. Meanwhile, the formation of aggregate states could not only induce both the luminescence and the chirality, but also further facilitate their enhancements, which resulted in the output and the modulation of desirable circularly polarized luminescence.

中文翻译:

更好:聚合引起的手性金簇的发光,出色的手性和圆极化发光

很好地证明了聚集诱导发射(AIE)效应对两个手性金簇R -1)S -1 的发光和手性的影响。它们的固态表现出极其明亮的磷光,量子产率超过70%。这两个簇在稀释溶液中没有发光和手性。同时,聚集态的形成不仅可以诱导发光和手性,而且可以进一步促进它们的增强,从而导致期望的圆偏振发光的输出和调制。
更新日期:2020-11-03
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