Petroleum Chemistry ( IF 1.4 ) Pub Date : 2020-10-08 , DOI: 10.1134/s0965544120100072 E. B. Markova , A. S. Lyadov , Yu. M. Serov , V. V. Kurilkin , A. G. Cherednichenko
To enhance the resistance of a metal-organic frameworks(MOF) to a change in the medium pH composite materials are synthesized from Cu-BTC (MOF-199) and activated carbons of various brands (AR-V, AGN-2, ART-1, BAU-A, MeKS). It is shown that the highest stability is exhibited by a material synthesized using activated carbon AR-V with the highest acidity of the surface as a matrix. The targeted increase in the acidity of the surface of carbon matrices due to their preliminary oxidation leads to the formation of metal-organic composite materials more resistant to acidic or alkaline media.
中文翻译:
由Cu-BTC(MOF-199)和活性炭合成耐中等酸度变化的复合材料
为了增强金属有机骨架(MOF)对中等pH值变化的抵抗力,使用Cu-BTC(MOF-199)和各种品牌(AR-V,AGN-2,ART- 1,BAU-A,MeKS)。结果表明,使用具有最高表面酸性的活性炭AR-V合成的材料表现出最高的稳定性。由于碳基质的初步氧化,有针对性地增加了碳基质表面的酸度,导致形成了对酸性或碱性介质更具抵抗力的金属有机复合材料。