Abstract

The effect of modification of a porous carbon material used to manufacture supercapacitors with a polymeric cobalt complex with a Salen-type Schiff base on the capacity of the material has been studied. Conjunction of multielectron redox processes in the polymer with the proposed effective modification technology makes it possible to increase the electrode capacity by 2.4 times in comparison with unmodified carbon electrodes. The specific capacity of the polymer poly-[Co(CH₃OSaltmen)] at a polymer deposition density of 1.3 mg cm^–2 was 170 mA h g^–1.

中文翻译：

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电化学超级电容器电极用Salen型席夫碱型Schiff碱聚合钴配合物修饰多孔碳材料

摘要

研究了使用具有Salen型席夫碱的聚合物钴配合物改性用于制造超级电容器的多孔碳材料对材料容量的影响。与未修饰的碳电极相比，聚合物中的多电子氧化还原工艺与所提出的有效修饰技术的结合使电极容量增加了2.4倍。在聚合物沉积密度为1.3 mg cm ^–2时，聚合物聚[[Co（CH ₃ OSaltmen）]]的比容量为170 mA hg ^–1。