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Recent advances and mechanistic insights on the production of biomass-derived 2,5-bis(alkoxymethyl)furans
Biomass Conversion and Biorefinery ( IF 4 ) Pub Date : 2020-10-08 , DOI: 10.1007/s13399-020-01062-9
Lei Hu , Yetao Jiang , Xiaoyu Wang , Aiyong He , Jiaxing Xu , Zhen Wu

Transforming biomass resources into high-quality liquid fuels is a very crucial, effective, and feasible approach in biorefinery processes. Among various biomass-derived liquid fuels, 2,5-bis(alkoxymethyl)furans (BAMFs), which can be produced from 2,5-bis(hydroxymethyl)furan (BHMF), 5-hydroxymethylfurfural (HMF), or fructose, are particularly attractive and widely considered to be a new type of biodiesel candidates or diesel additives due to their excellent physicochemical properties, such as high energy density, high cetane number, high boiling point, and strong stability, so they have received wide attention in recent years. At present, the relevant studies on the production of BAMFs are rapidly implementing, many progressive techniques are constantly developed and satisfactory results are increasingly obtained. However, up to now, a special, systematic and intensive review is still lacking in this research area. To better understand the current research situation, this review comprehensively summarizes and discusses different production methods and corresponding achievements of BAMFs, and emphatically analyzes the main functions and cooperative actions of active sites of catalysts in dehydration, reduction, and etherification reactions as well as the merits and demerits of exogenous and endogenous hydrogen systems. Moreover, this review also proposes several valuable and available ideas and viewpoints for the future studies of BAMFs. In a word, the main objective of this review is to draw more concerns about BAMFs and provide some theoretical references and technical supports for the high-efficiency, green, and economical production of BAMFs.



中文翻译:

生产生物质衍生的2,5-双(烷氧基甲基)呋喃的最新进展和机理见解

在生物精炼过程中,将生物质资源转化为高质量的液体燃料是一种非常关键,有效和可行的方法。在各种生物质衍生的液体燃料中,可以由2,5-双(羟甲基)呋喃(BHMF),5-羟甲基糠醛(HMF)或果糖生产的2,5-双(烷氧基甲基)呋喃(BAMF)。高能量密度,十六烷值高,沸点高,稳定性强等优异的理化特性,特别吸引人,被广泛认为是新型的生物柴油候选物或柴油添加剂,因此近年来受到了广泛关注。目前,有关BAMFs生产的相关研究正在迅速实施,许多先进技术不断发展,并且取得了令人满意的结果。但是,到目前为止,该研究领域仍然缺乏系统和深入的审查。为了更好地了解当前的研究现状,本综述全面总结和讨论了BAMFs的不同生产方法和取得的成就,并着重分析了催化剂活性部位在脱水,还原和醚化反应中的主要功能和协同作用以及优点。和外源和内源氢系统的缺点。此外,本综述还为BAMF的未来研究提出了一些有价值的和可用的想法和观点。总之,本次综述的主要目的是引起对BAMF的更多关注,并为BAMF的高效,绿色和经济生产提供一些理论参考和技术支持。

更新日期:2020-10-11
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