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Stereoselective synthesis towards (+)-trans-kumausyne employing vinylogous Mukaiyama type reaction on an α-chloro sulfide
Indian Journal of Chemistry, Section B ( IF 0.456 ) Pub Date : 2020-10-05
L Raju Chowhan, Sadagopan Raghavan

A stereoselective synthesis towards (+)-trans-kumausyne is disclosed. The key steps of the synthesis include stereoselective C-C formation employing vinylogous Mukaiyama type reaction of an α-chloro sulfide with 2-trimethylsiloxy furan and base-catalyzed isomerization followed by intramolecular oxa-Michael reaction.

中文翻译:

在α-氯硫化物上使用乙烯基类Mukaiyama型反应对(+)-反-kumausyne的立体选择性合成

公开了一种对(+)-反式-熊果嘧啶的立体选择性合成。合成的关键步骤包括使用α-氯硫化物与2-三甲基甲硅烷氧基呋喃的乙烯基Mukaiyama型反应和碱催化的异构化以及随后的分子内oxa-Michael反应形成立体选择性CC。
更新日期:2020-10-05
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