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Effect of settling time on the adsorption of 137Cs onto AMP in the AMP-coprecipitation method
Marine Pollution Bulletin ( IF 5.8 ) Pub Date : 2020-10-03 , DOI: 10.1016/j.marpolbul.2020.111713
Fangfang Deng , Jianhua He , Feng Ling , Wen Yu , Wu Men , Fenfen Wang

Ten sets of experiments with different settling times were conducted to investigate the effect of settling time on the adsorption of 137Cs in seawater onto ammonium phosphomolybdate (AMP). The weight yields of AMP and 137Cs yields in all groups were generally higher than 90%. The average weight yields of AMP in each group varied from 91.8 ± 0.5 to 95.9 ± 0.6% (1 SD), and the average 137Cs yields in each group varied from 88.3 ± 3.0 to 97.8 ± 3.7% (1 SD). The results showed that equilibrium between Cs and AMP is established immediately after the addition of stable Cs carrier and AMP, implying that the solution could be filtered immediately after the coprecipitation forms. IAEA seawater proficiency test exercises also confirmed that the AMP precipitate does not need to be treated statically in the case of 2 g AMP and 3.7 mg Cs carrier in a seawater sample solution. The modified AMP preconcentration method simultaneously meets the requirements of routine and nuclear emergency monitoring of 137Cs in seawater.



中文翻译:

AMP共沉淀法中稳定时间对137 Cs在AMP上吸附的影响

进行了十组具有不同沉降时间的实验,以研究沉降时间对海水中137 Cs吸附在磷钼酸铵(AMP)上的影响。所有组中AMP的重量产率和137 Cs的产率通常高于90%。每组AMP的平均产量为91.8±0.5%至95.9±0.6%(1 SD),平均137每组的Cs产量从88.3±3.0到97.8±3.7%(1 SD)不等。结果表明,在加入稳定的Cs载体和AMP后立即建立Cs和AMP之间的平衡,这意味着在共沉淀形成后可以立即过滤溶液。IAEA海水能力测试还证实,在海水样品溶液中使用2 g AMP和3.7 mg Cs载体时,无需对AMP沉淀物进行静态处理。改进后的AMP预富集方法同时满足了对海水中137 Cs的常规监测和核应急监测的要求。

更新日期:2020-10-04
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