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Sensitive and Selective Detection of Cu2+ and Pb2+ Ions Using Field Effect Transistor (FET) Based on L-Cysteine Anchored PEDOT:PSS/rGO Composite
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-10-03 , DOI: 10.1016/j.cplett.2020.138056
Pasha W. Sayyad , Nikesh N. Ingle , Theeazen Al-Gahouari , Manasi M. Mahadik , Gajanan A. Bodkhe , Sumedh M. Shirsat , Mahendra D. Shirsat

Herein, Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)/reduced graphene oxide (rGO) (PEDOT:PSS/rGO) composite was prepared and further functionalized with L-Cysteine (LC) to manifest sensitive and selective detection of copper (Cu2+) and lead (Pb2+) ions using Field Effect Transistor (FET) in the concentration range of 1-60 µg/L. The sensor (PEDOT:PSS/rGO/L-Cysteine) exhibits low-voltage operations, highly sensitive and selective towards target metal ions (Cu2+ and Pb2+). The lower detection limits for Cu2+ and Pb2+ were found to be 0.33 µg/L and 2.36 µg/L, which is well below the World Health Organization WHO recommendations (2 mg/L (2 ppm) for Cu2+ ions and 10 µg/L (10 ppb) for Pb2+ ions.



中文翻译:

使用基于L-半胱氨酸的PEDOT:PSS / rGO复合材料的场效应晶体管(FET)灵敏和选择性地检测Cu 2+和Pb 2+离子

在此,制备了聚(3,4-乙撑二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT:PSS)/还原氧化石墨烯(rGO)(PEDOT:PSS / rGO)复合材料,并用L-半胱氨酸(LC)进一步官能化以显示敏感并使用场效应晶体管(FET)在1-60 µg / L的浓度范围内选择性检测铜(Cu 2+)和铅(Pb 2+)离子。传感器(PEDOT:PSS / rGO / L-Cysteine)具有低电压操作,对目标金属离子(Cu 2+和Pb 2+)具有高度的敏感性和选择性。发现Cu 2+和Pb 2+的最低检测限为0.33 µg / L和2.36 µg / L,远低于世界卫生组织的WHO建议(Cu的2 mg / L(2 ppm))2+离子和10μg/ L(10 ppb)的Pb 2+离子。

更新日期:2020-10-04
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