Abstract

Based on a joint review and discussion of data on the ignition of aldehyde–oxygen mixtures, initiated by an adsorbed peroxide compound upon heating, and on the heterogeneous interaction between RO₂ peroxide radicals and an aldehyde, it is concluded that the constant temperature T_i of ignition in one range of changes in the amount of peroxide compound is due to the limited number of active centers on its surface because of its saturation with heterogeneous radical reactions.

中文翻译：

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吸附的过氧化物化合物引发的脂肪醛与氧气的混合物着火

摘要

基于对由加热时吸附的过氧化物化合物引发的醛-氧混合物着火以及RO ₂过氧化物自由基与醛之间的异质相互作用的数据进行的联合审查和讨论，得出的结论是恒温T _i在过氧化物化合物的量的一个变化范围内的起燃的原因是由于其表面上的活性中心数量有限，这是由于其被异质自由基反应所饱和。