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Identification of vicinal diols using a diagnostic ion derived from the electron ionization of orthoester functional groups
Rapid Communications in Mass Spectrometry ( IF 2 ) Pub Date : 2020-10-02 , DOI: 10.1002/rcm.8930
Renzo Alexander Samame 1 , Chengli Zu 1 , Daniel Knueppel 1
Affiliation  

During production of the article by Samame et al1 errors were introduced in Table 1. Many of the substrates and diagnostic product ions were misplaced. In addition, the headings of the final two columns were run together as ‘Theoretical measured’ when they should be separate headings, ‘Theoretical’ and ‘Measured’. The corrected table is provided here.

TABLE 1. Substrate scope and corresponding [diol + 39]+ diagnostic ions of derivatized products. Theoretical masses for the most abundant isotopologues are shown. Ratios were determined by peak area % normalization, integrating only the peaks arising from the two orthoesters 3 and 4
chemical structure image
Entry Substrate Mass [M] Ratio Diagnostic Mass [diol + 39]+
Theoretical 3:4 Production Theoretical Measured
1 chemical structure image 102.0681 2:98 chemical structure image 141.0910 141.0911
2 chemical structure image 170.1307 81:19 chemical structure image 209.1536 209.1537
3 chemical structure image 104.0473 51:49 chemical structure image 143.0703 143.0702
4 chemical structure image 90.0681 32:68 chemical structure image 129.0910 129.0910
5 chemical structure image 180.1150 72:28 chemical structure image 219.1380 219.1380
6 chemical structure image 110.0368 100:0 chemical structure image 149.0597 149.0597
7 chemical structure image 214.0994 4:96 chemical structure image 253.1223 253.1224
8 chemical structure image 138.0681 48:52 chemical structure image 177.0910 177.0910


中文翻译:

使用源自原酸酯官能团电子电离的诊断离子鉴定邻二醇

在生产过程中的文章Samame等人的1点在表1中引入的误差的许多底物和诊断产物离子被放错了地方。另外,当最后两列的标题应分别为“理论”和“已测量”时,它们以“理论测量”形式一起运行。此处提供了更正的表。

表1.衍生产物的底物范围和相应的[二醇+ 39] +诊断离子。显示了最丰富的同位素同位素的理论质量。比率由峰面积%归一化确定,仅对两个原酸酯34产生的峰进行积分
化学结构图
条目 基质 质量[M] 诊断 质量[二醇+ 39] +
理论上的 3:4 生产 理论上的 实测
1个 化学结构图 102.0681 2:98 化学结构图 141.0910 141.0911
2 化学结构图 170.1307 81:19 化学结构图 209.1536 209.1537
3 化学结构图 104.0473 51:49 化学结构图 143.0703 143.0702
4 化学结构图 90.0681 32:68 化学结构图 129.0910 129.0910
5 化学结构图 180.1150 72:28 化学结构图 219.1380 219.1380
6 化学结构图 110.0368 100:0 化学结构图 149.0597 149.0597
7 化学结构图 214.0994 4:96 化学结构图 253.1223 253.1224
8 化学结构图 138.0681 48:52 化学结构图 177.0910 177.0910
更新日期:2020-10-02
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