To enhance anti‐migratory performance and combustion catalytic activities of neutral ferrocene‐based burning rate catalysts (BRCs), nine ferrocenyl 1,2,3‐triazolyl compounds of anilines and aliphatic amines (Fc‐ATAZs, 1–9) were synthesized by click reaction and characterized by NMR, UV/Vis, FT‐IR, and MS. TG and DSC studies confirmed that the Fc‐ATAZs are highly thermal stable. Cyclic voltammetry results implied that 1 and 6 are reversible redox systems. The anti‐migration and anti‐volatility tests showed that the Fc‐ATAZs are low‐migratory and low‐volatile compounds.Combustion catalytic activity results of the Fc‐ATAZs revealed that they are highly active for promoting thermal disintegration of AP, RDX and HMX. Compounds 3, 2 and 8 can increase released heats of AP, RDX and HMX, respectively, by 132 %, 112 % and 36 %, respectively, being the highest in each case. Most of them are more active than the reported analogs derived from phenols and benzoic acids. They, except 9, are more active than catocene and can be used as potential BRCs in composite solid propellants.

中文翻译：

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点击反应合成苯胺和烷基胺二茂铁化合物的抗迁移和燃烧催化性能

为了提高中性二茂铁基燃烧速率催化剂（BRC）的抗迁移性能和燃烧催化活性，通过点击合成了九种苯胺和脂肪胺的二茂铁基1,2,3-三唑基化合物（Fc-ATAZs，1 – 9）。反应并通过NMR，UV / Vis，FT-IR和MS进行表征。TG和DSC研究证实Fc-ATAZ具有高度的热稳定性。循环伏安法结果表明1和6是可逆氧化还原系统。抗迁移和抗挥发性测试表明Fc‐ATAZs是低迁移和低挥发性的化合物.Fc‐ATAZs的燃烧催化活性结果表明它们对促进AP，RDX和HMX的热分解具有很高的活性。 。化合物图3，图2和图8可分别将AP，RDX和HMX的释放热量分别增加132％，112％和36％，这是每种情况下的最高值。它们中的大多数比报道的衍生自苯酚和苯甲酸的类似物更具活性。除9外，它们的活性都比新世时代高，可以用作复合固体推进剂中潜在的BRC。