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One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones
Green Synthesis and Catalysis Pub Date : 2020-07-27 , DOI: 10.1016/j.gresc.2020.05.001 Xixi Song , Yueteng Zhang , Peng Ji , Fanxun Zeng , Fangchao Bi , Wei Wang
中文翻译:
含二芳基水杨醛框架之一一锅法合成经由ynals与2-吡喃酮的aminocatalytic狄尔斯-阿尔德-逆狄尔斯-阿尔德反应级联
更新日期:2020-09-29
Green Synthesis and Catalysis Pub Date : 2020-07-27 , DOI: 10.1016/j.gresc.2020.05.001 Xixi Song , Yueteng Zhang , Peng Ji , Fanxun Zeng , Fangchao Bi , Wei Wang
Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields. The reaction is instrumentally metal-free, operationally simple and mild, and tolerates a diverse array of functional groups.
中文翻译:
含二芳基水杨醛框架之一一锅法合成经由ynals与2-吡喃酮的aminocatalytic狄尔斯-阿尔德-逆狄尔斯-阿尔德反应级联
含有水杨醛的联芳基可通过空前的胺与2-吡喃酮进行的空前的胺促进的Diels-Alder-retro-Diels-Alder级联反应有效合成。该反应在仪器上不含金属,操作简单且温和,并且可耐受各种官能团。