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Synthesis of new siloxane or sulfur containing symmetrical monomers based on carvone
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.3 ) Pub Date : 2020-09-25 , DOI: 10.1080/10426507.2020.1804141 Fedor V. Drozdov 1 , Georgij V. Cherkaev 1 , Aziz M. Muzafarov 1, 2
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.3 ) Pub Date : 2020-09-25 , DOI: 10.1080/10426507.2020.1804141 Fedor V. Drozdov 1 , Georgij V. Cherkaev 1 , Aziz M. Muzafarov 1, 2
Affiliation
Abstract We demonstrated, that based on carvone, new symmetrical AA-type monomers with double bonds can be easily prepared by thiol-ene or Michael addition of dithiols. Moreover, hydrosilylation reaction with difunctional telehelic siloxane, containing Si-H groups was also studied. Obtained monomers are suitable for further polymerization by thiol-ene or hydrosilylation polyaddition. GRAPHICAL ABSTRACT
中文翻译：
基于香芹酮的新型含硅氧烷或硫对称单体的合成
摘要 我们证明，基于香芹酮，可以通过硫醇-烯或二硫醇的迈克尔加成轻松制备具有双键的新型对称AA型单体。此外，还研究了与含有 Si-H 基团的双官能遥螺旋硅氧烷的氢化硅烷化反应。得到的单体适合通过硫醇-烯或氢化硅烷化加聚进一步聚合。图形概要
更新日期：2020-09-25
中文翻译：
基于香芹酮的新型含硅氧烷或硫对称单体的合成
摘要 我们证明，基于香芹酮，可以通过硫醇-烯或二硫醇的迈克尔加成轻松制备具有双键的新型对称AA型单体。此外，还研究了与含有 Si-H 基团的双官能遥螺旋硅氧烷的氢化硅烷化反应。得到的单体适合通过硫醇-烯或氢化硅烷化加聚进一步聚合。图形概要
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