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Reaction of germabenzenylpotassium with TBDMSCl: Unusual trimerization of germabenzene skeletons
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.3 ) Pub Date : 2020-09-25 , DOI: 10.1080/10426507.2020.1804187
Yoshiyuki Mizuhata 1, 2 , Shiori Fujimori 1, 3 , Norihiro Tokitoh 1, 2
Affiliation  

Abstract The reaction of 2-t-Bu-germabenzenylpotassium with Me2(t-Bu)SiCl (TBDMSCl) resulted in the coupling among two TBDMS-substituted germabenzenes and the germabenzenylpotassium. The structure of the product was determined by X-ray crystallographic analysis. Its formation mechanism was proposed with the help of theoretical calculations. Graphical Abstract

中文翻译:

锗苄基钾与 TBDMSCl 的反应:锗苯骨架的异常三聚化

摘要 2-t-Bu-锗苄基钾与Me2(t-Bu)SiCl (TBDMSCl) 的反应导致两种TBDMS 取代的锗苯和锗苄基钾之间的偶联。通过X-射线晶体学分析确定产物的结构。其形成机制是在理论计算的帮助下提出的。图形概要
更新日期:2020-09-25
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