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Rapid and Selective Removal of Cs+ from Water by Layered Potassium Antimony Thiostannate
Journal of Hazardous Materials ( IF 13.6 ) Pub Date : 2020-09-25 , DOI: 10.1016/j.jhazmat.2020.124105
Chenyang Yang , Kuk Cho

137Cs is radioactive and highly hazardous to human health and the environment and its efficient removal from water is still challenging. In this study, potassium antimony tin sulfide (KATS-2) was synthesized using a hydrothermal method and utilized for the first time for cesium removal from water. KATS-2 showed a high maximum ion exchange capacity (358 mg g-1) and distribution coefficient (1.59 × 105 mL g-1) toward Cs+. In particular, KATS-2 showed rapid ion exchange kinetics and reached the adsorption equilibrium within 5 min with 99% removal efficiency. The adsorption was good at a wide active pH range (1–12) even in extreme alkaline conditions (Kd = 3.26 × 104 mL g-1 at pH 12). The effect of coexisting ions was also investigated, and a high selectivity toward Cs+ was maintained even in artificial seawater (Kd = 3.28 × 103 mL g-1).Powder X-ray diffraction and thermogravimetric analysis demonstrated that KATS-2 was chemically and thermally stable. The results showed that owing to its excellent adsorption performance as well as chemical and thermal stability, KATS-2 is a promising adsorbent for Cs+ removal from contaminated water.



中文翻译:

层状硫锡酸钾锑快速选择性去除水中的Cs +

137 Cs具有放射性,对人体健康和环境具有高度危害,如何有效地将其从水中清除仍然具有挑战性。在这项研究中,使用水热法合成了锑化锡锑钾(KATS-2),并首次用于从水中去除铯。KATS-2具有很高的最大离子交换容量(358 mg g -1)和分配系数(1.59)×向Cs +注入10 5  mL g -1)。尤其是,KATS-2显示出快速的离子交换动力学,并在5分钟内达到了吸附平衡,去除效率为99%。即使在极端碱性条件下(K d = 3.26 ),在宽的活性pH范围(1–12)下也具有良好的吸附×10 4  mL g -1(pH 12)。还研究了共存离子的影响,即使在人工海水中(K d = 3.28)也能保持对Cs +的高选择性。×10 3  mL g -1)。粉末X射线衍射和热重分析表明,KATS-2具有化学和热稳定性。结果表明,由于其出色的吸附性能以及化学和热稳定性,KATS-2是一种有望从污染水中去除Cs +的吸附剂。

更新日期:2020-09-25
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