Dess–Martin periodinane (DMP), a commercially available chemical, is frequently utilized as a mild oxidative agent for the selective oxidation of primary and secondary alcohols to their corresponding aldehydes and ketones, respectively. DMP shows several merits over other common oxidative agents such as chromiumand DMSO-based oxidants; thus, it is habitually employed in the total synthesis of natural products. In this review, we try to underscore the applications of DMP as an effective oxidant in an appropriate step (steps) in the multi-step total synthesis of natural products.

中文翻译：

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Dess-Martin氧化法在天然产物全合成中的应用

Dess-Martin高碘烷（DMP）是一种市售化学品，经常被用作温和氧化剂，用于将伯醇和仲醇分别氧化为相应的醛和酮。与其他常见氧化剂（例如铬和DMSO基氧化剂）相比，DMP具有几个优点。因此，习惯上将其用于天然产物的全合成中。在这篇综述中，我们试图强调在天然产物的多步全合成的适当步骤（步骤）中，DMP作为有效氧化剂的应用。