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Using Synthetic Chelating Agents to Decrease Phosphorus Binding in Soils
Soil Science ( IF 1.692 ) Pub Date : 2016-08-01 , DOI: 10.1097/ss.0000000000000171
Cristie L. Edwards , Rory O. Maguire , Garnett B. Whitehurst , Wade E. Thomason , Mark M. Alley

Abstract Most acid soils have a high capacity to bind phosphorus (P) strongly on iron (Fe) and aluminum (Al) hydroxides, resulting in low P fertilizer use efficiency. Organic chelating agents form strong bonds with metals in soil and may reduce P binding with Fe and Al and increase fertilizer P use efficiency. Ethylenediamine tetraacetic acid (EDTA), hydroxyethyl ethylenediamine triacetic acid (HEEDTA), gluconic acid, and citric acid were tested to determine their influence on water-soluble P (WSP), Mehlich-1 P, and Mehlich-3 P in a loam and sand fertilized with P and incubated for 49 days. Soil P sorption capacity (PSC) was estimated from an oxalate extraction of Fe and Al, and chelates were applied at rates of 90% of the PSC. EDTA and HEEDTA were also applied at 0, 30, 60, 90, 120, and 150% PSC to produce a rate response curve for WSP in a second soil incubation. The EDTA, HEEDTA, and citric acid significantly (P < 0.05) reduced P sorption in the loam and sand when measured by WSP. In soils without P fertilizer added, EDTA and HEEDTA resulted in a significant increase in WSP concentrations, as well as increased concentrations of Mehlich-1 P and Mehlich-3 P. With increasing chelation rates of EDTA and HEEDTA, there was a linear increase in WSP for both soils, indicating higher rates were most effective at decreasing P sorption. The application of chelating agents, with and without P fertilizer, could potentially increase plant availability of P, therefore reducing P fertilizer.

中文翻译:

使用合成螯合剂降低土壤中磷的结合

摘要 大多数酸性土壤对铁(Fe)和铝(Al)的氢氧化物具有很强的结合磷(P)的能力,导致磷肥利用率低。有机螯合剂与土壤中的金属形成强键,可以减少磷与铁和铝的结合,提高肥料磷的利用率。测试了乙二胺四乙酸 (EDTA)、羟乙基乙二胺三乙酸 (HEEDTA)、葡萄糖酸和柠檬酸,以确定它们对壤土中水溶性磷 (WSP)、Mehlich-1 P 和 Mehlich-3 P 的影响。用 P 施肥的沙子并培养 49 天。土壤 P 吸附能力 (PSC) 是通过草酸盐提取 Fe 和 Al 估算的,螯合物的施用率为 PSC 的 90%。EDTA 和 HEEDTA 也在 0、30、60、90、120、和 150% PSC 在第二次土壤培养中产生 WSP 的速率响应曲线。当用 WSP 测量时,EDTA、HEEDTA 和柠檬酸显着(P < 0.05)降低了壤土和沙子中的 P 吸附。在未添加 P 肥料的土壤中,EDTA 和 HEEDTA 导致 WSP 浓度显着增加,以及 Mehlich-1 P 和 Mehlich-3 P 浓度增加。随着 EDTA 和 HEEDTA 螯合率的增加,WSP 浓度呈线性增加两种土壤的 WSP,表明较高的速率在减少 P 吸附方面最有效。螯合剂的应用,无论有没有磷肥,都可能增加植物对磷的利用率,从而减少磷肥。在未添加 P 肥料的土壤中,EDTA 和 HEEDTA 导致 WSP 浓度显着增加,以及 Mehlich-1 P 和 Mehlich-3 P 浓度增加。随着 EDTA 和 HEEDTA 螯合率的增加,WSP 浓度呈线性增加两种土壤的 WSP,表明较高的速率在减少 P 吸附方面最有效。螯合剂的应用,无论有没有磷肥,都可能增加植物对磷的利用率,从而减少磷肥。在未添加 P 肥料的土壤中,EDTA 和 HEEDTA 导致 WSP 浓度显着增加,以及 Mehlich-1 P 和 Mehlich-3 P 浓度增加。随着 EDTA 和 HEEDTA 螯合率的增加,WSP 浓度呈线性增加两种土壤的 WSP,表明较高的速率在减少 P 吸附方面最有效。螯合剂的应用,有和没有磷肥,可能会增加植物对磷的利用率,从而减少磷肥。
更新日期:2016-08-01
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