当前位置: X-MOL 学术Lett. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
2,5-Dihydroxyterephthalic Acid Accelerated Cu(NO3)2.3H2O-Catalyzed Homocoupling Reaction of Arylboronic Acids
Letters in Organic Chemistry ( IF 0.8 ) Pub Date : 2020-10-31 , DOI: 10.2174/1570178617666200210110041
Fengtian Wu 1 , Chenlong Nan 1 , Jianwei Xie 2 , Mingyang Ma 1
Affiliation  

A catalyst system derived from commercially available Cu(NO3)2.3H2O and 2,5- dihydroxyterephthalic acid is applied to the homocoupling reaction of arylboronic acids. This transformation provides a convenient approach to symmetrical biaryls with good to excellent yields (39%- 95%), and exhibits good functional group compatibility. Furthermore, biaryl can be prepared in gram quantities in good yield.



中文翻译:

2,5-二羟基对苯二甲酸促进Cu(NO 32 .3H 2 O催化芳基硼酸的均偶联反应

将衍生自市售的Cu(NO 32 .3H 2 O和2,5-二羟基对苯二甲酸的催化剂体系用于芳基硼酸的均偶联反应。这种转化为对称的联芳基化合物提供了一种方便的方法,具有良好至极好的收率(39%-95%),并具有良好的官能团相容性。此外,联芳基可以以克的量高收率地制备。

更新日期:2020-12-01
down
wechat
bug