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Enhanced Methylene Blue Removal Efficiency of TiO2 Embedded Porous Glass
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-09-23 , DOI: 10.1016/j.jeurceramsoc.2020.09.047
E. Burak Ertuş , Cekdar Vakifahmetoglu , Abdullah Öztürk

A porous glass (PG) embedded with titanium dioxide (TiO2) was produced via impregnation of the PG with Titanium (IV) Isopropoxide solution followed by crystallization. N2 sorption analyses revealed that the specific surface area (SSA) and total pore volume of the PG reached to 358 m2/g and 0.370 cm3/g, respectively. The adsorption capacity of methylene blue (MB) for the glasses was measured in the dark, instead the photocatalytic MB removal efficiency was evaluated by the degradation of MB under UV light illumination using a UV-Vis spectrometer. The MB removal efficiency of the TiO2 synthesized anatase powder was only 32.3% whereas, for TiO2 embedded PG (TiPG) it was 91.6%, and nearly complete (> 99%) efficacy was achieved for TiO2 embedded alkaline leached PG (TiPG-AL) under UV illumination 3 h period. Better MB removal efficiency was attributed to high SSA and dispersion of nano size anatase TiO2 crystallites within the porous structure.



中文翻译:

TiO 2嵌入式多孔玻璃的亚甲蓝去除效率提高

通过用异丙醇钛(IV)溶液浸渍PG,然后进行结晶,制造出嵌有二氧化钛(TiO 2)的多孔玻璃(PG)。N 2吸附分析表明,PG的比表面积(SSA)和总孔体积分别达到358 m 2 / g和0.370 cm 3 / g。在黑暗中测量了玻璃对亚甲蓝(MB)的吸附能力,取而代之的是通过使用UV-Vis光谱仪在UV照明下MB的降解来评估光催化MB的去除效率。TiO 2合成的锐钛矿粉的MB去除率仅为32.3%,而对于TiO 2嵌入式PG(TiPG -AL)为91.6%,在紫外线照射3 h下,TiO 2嵌入式碱性浸出PG(TiPG-AL)的功效几乎完全(> 99%)。较高的MB去除效率归因于较高的SSA和纳米结构的锐钛矿型TiO 2微晶在多孔结构内的分散。

更新日期:2020-09-23
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