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Synthesis of 3-and 2,3-substituted pyrazolo[1,5- a ][1,10]phenanthrolines
Chemistry of Heterocyclic Compounds ( IF 1.5 ) Pub Date : 2020-09-23 , DOI: 10.1007/s10593-020-02772-8
Viktoriya А. Sannikova , Igor R. Filippov , Oleg Yu. Karmatskikh , Mikhail А. Panfilov , Rodion V. Andreev , Aleksey Yu. Vorob’ev

The reaction of N-amino-1,10-phenanthrolinium mesitylenesulfonate with acceptor-substituted alkenes in the K2CO3–DMSO system gave 3- and 2,3-substituted pyrazolo[1,5-a][1,10]phenanthrolines. A wide range of alkenes enter into this reaction; however, in the case of nitro derivatives, complex mixtures of products were formed.



中文翻译:

3-和2,3-取代的吡唑并[1,5-a] [1,10]菲咯啉的合成

的反应ñ -氨基-1,10-菲咯啉均三甲苯磺酸盐具有受体基取代的烯烃在K 2 CO 3 -DMSO系统得到3-和2,3-取代的吡唑并[1,5-一个] [1,10]菲咯啉。各种各样的烯烃进入该反应。但是,在硝基衍生物的情况下,形成了复杂的产物混合物。

更新日期:2020-09-23
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