Noble metals supported on ZrO₂ catalysts were elaborated using sol-gel and impregnation methods then studied for catalytic wet air oxidation of bisphenol-A (BPA) in water. The prepared solids were characterized by N₂-physisorption at 77 k, XRD, TEM, TGA/TDA, FTIR spectroscopy, XPS and H₂-TPR techniques. BPA solution of 10 mg/L was successfully oxidized at 100 °C and P_air = 20 bar. For pure ZrO₂, a conversion of 49% was obtained within 5 h. The catalytic activity was improved by adding noble metals resulting in a BPA conversion surpassing 90% for 3%Ru/ZrO₂ after 3 h. No catalyst deactivation was reported.

使用溶胶-凝胶和浸渍方法对负载在ZrO ₂催化剂上的贵金属进行了精细加工，然后研究了其在水中对双酚A（BPA）的催化湿式空气氧化。通过77k的N _2-物理吸附，XRD，TEM，TGA / TDA，FTIR光谱，XPS和H ₂ -TPR技术表征制备的固体。10 mg / L的BPA溶液在100°C和P _air  = 20 bar下成功氧化。对于纯ZrO ₂，在5小时内转化率为49％。通过添加贵金属提高了催化活性，导致3小时后3 ％Ru / ZrO ₂的BPA转化率超过90％。没有催化剂失活的报道。