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Eco friendly Synthesis of the LiY(MoO4)2 Coral-Like Quantum Dots in Biotemplate MOF (QD/BioMOF) for in vivo imaging and Ibuprofen Removal from an Aqueous Media study
Arabian Journal of Chemistry ( IF 6 ) Pub Date : 2020-11-01 , DOI: 10.1016/j.arabjc.2020.09.013
Fahimeh Asadi , Hamid Forootanfar , Mehdi Ranjbar , Ali Asadipour

Abstract Here as the first new research study on the bio quantum dots on metal–organic frameworks (BQDMOFs), we synthesized coral-like LiY(MoO4)2 BQDMOFs with hydrothermal method as an eco-friendly and cost effective approach. The lecithin as complex mixtures of lipids such as phospholipids which was extracted from egg yolk was applied not only as emulsifier for the formation of LiY(MoO4)2 quantum dots, but also acts as organic ligand and auxiliary linker agent on the base structure of the organic frameworks. The effect of such factors as pH (3–11), show with increasing pH from 3 up to 11 solubility increases and as a result the ibuprofen removal increases.The BQDMOFs structures were synthesized on the base of an organic frameworks with coral-like morphology with diameter in a range about 8–20 nm. The physicochemical properties, Ibuprofen removal from an aqueous media and in vivo imaging studies were investigated on the LiY(MoO4)2 BQDMOFs structures. Final products were characterization with analyze nanoparticle size using the well-known technique of dynamic light scattering (DLS), High-performance thin-layer chromatography (HPTLC), Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Infrared spectroscopy (IR) and the UV–Visible spectrum. From the sum of the results it can be established that LiY(MoO4)2 BQDMOFs structures acts not only as a super-radiant photoluminescence (SRP) substance for use in in vivo imaging in small animal researches but also as a surface-specific material which can be use in removal of ibuprofen drug from an aqueous media. The photocatalyst results of the LiY(MoO4)2 BQDMOFs shows high removal efficiency of ibuprofen (more than 99%) after 60 min under the UV light.

中文翻译:

生物模板 MOF (QD/BioMOF) 中 LiY(MoO4)2 珊瑚状量子点的生态友好合成,用于体内成像和从水介质研究中去除布洛芬

摘要 作为对金属有机骨架 (BQDMOF) 上生物量子点的首次新研究,我们采用水热法合成了珊瑚状 LiY(MoO4)2 BQDMOF,作为一种环保且具有成本效益的方法。卵磷脂是从蛋黄中提取的磷脂等脂质的复杂混合物,不仅作为乳化剂用于形成 LiY(MoO4)2 量子点,而且作为有机配体和辅助连接剂作用于基体结构上。有机框架。pH (3-11) 等因素的影响表明,随着 pH 从 3 增加到 11,溶解度增加,因此布洛芬去除率增加。 BQDMOFs 结构是在具有珊瑚状形态的有机骨架的基础上合成的直径在 8-20 nm 范围内。理化性质,在 LiY(MoO4)2 BQDMOFs 结构上研究了布洛芬从水性介质中的去除和体内成像研究。使用众所周知的动态光散射 (DLS)、高效薄层色谱 (HPTLC)、粉末 X 射线衍射 (XRD)、扫描电子显微镜 (SEM)、透射技术,通过分析纳米颗粒尺寸对最终产品进行表征电子显微镜 (TEM)、红外光谱 (IR) 和紫外-可见光谱。从结果的总和可以确定,LiY(MoO4)2 BQDMOFs 结构不仅作为超辐射光致发光 (SRP) 物质用于小动物研究的体内成像,而且作为表面特异性材料可用于从水性介质中去除布洛芬药物。
更新日期:2020-11-01
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