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Catalysis and regioselectivity in hydrofunctionalization reactions of unsaturated carbon bonds. Part II. Hydroamination
Russian Chemical Reviews ( IF 7.7 ) Pub Date : 2020-09-18 , DOI: 10.1070/rcr4953
Irina P. Beletskaya 1 , Carmen Najera 2 , Miguel Yus 2
Affiliation  

This review continues consideration of the regioselectivity problem in the catalyzed hydrofunctionalization of unsaturated organic compounds and addresses hydroamination of unsaturated hydrocarbons. Particular parts of the review deal with reactions of alkenes, alkynes, allenes and dienes. It is shown that the selectivity of hydroamination depends on the natures of the reactants and the catalyst. Conditions of the reactions are described; in some cases, reaction mechanisms are discussed. Reactions for which divergent regioselectivity is possible are noted.

The bibliography includes 249 references.

Dedicated to the memory of V.V.Markovnikov.



中文翻译:

不饱和碳键加氢官能化反应中的催化和区域选择性。第二部分。加氢胺化

本综述继续考虑不饱和有机化合物的催化加氢官能化中的区域选择性问题,并解决不饱和烃的加氢胺化问题。评论的特定部分涉及烯烃、炔烃、丙二烯和二烯烃的反应。结果表明,加氢胺化的选择性取决于反应物和催化剂的性质。描述了反应条件;在某些情况下,讨论了反应机制。注意到可能具有不同区域选择性的反应。

参考书目包括 249 篇参考文献。

献给VVMarkovnikov的记忆。

更新日期:2020-09-18
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