A deoxygenative 1,1‐bis‐trifluoromethylthiolation of readily available aromatic aldehydes with AgSCF₃ in the presence of KI and (NH₄)₂SO₄ was established. This reaction delivered a series of bis(trifluoromethylthio)methylarenes in moderate to high yields. The precise control of the generation and decomposition of SCF₃ anion is the key to the successful transformation.

中文翻译：

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芳香醛的脱氧1,1-双-三氟甲基硫醇化反应制得双（三氟甲硫基）甲基芳烃

在KI和（NH ₄）₂ SO ₄存在下，用AgSCF ₃对易得的芳族醛进行了脱氧1,1-双-三氟甲基硫醇化反应。该反应以中等至高产率递送了一系列双（三氟甲硫基）甲基芳烃。精确控制SCF ₃阴离子的生成和分解是成功转化的关键。