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Solid-state solar cells co-sensitized with PbS/CdS quantum dots and N719 dye and based on solid polymer electrolyte with binary cations and nanofillers
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.3 ) Pub Date : 2020-09-18 , DOI: 10.1016/j.jphotochem.2020.112915
M.A.K.L. Dissanayake , T. Jaseetharan , G.K.R. Senadeera , B-E. Mellander , I. Albinsson , M. Furlani , J.M.K.W. Kumari

Co-sensitized solar cells have gained more attention due to the ability of energy conversion process by absorbing photons from wide range of the solar spectrum including visible and near-infrared region. TiO2 electrodes were co-sensitized with PbS/CdS core-shell quantum dots and N719 dye. PbS/CdS/N719 dye-sensitized solar cells were fabricated with poly(ethylene oxide) based solid polymer electrolyte consisting iodide/triiodide redox couple. The iodide ion conductivity of the electrolyte was enhanced by incorporating a binary iodide salt mixture of different size cations, tetrapropylammonium iodide and potassium iodide. The performance of the solar cell was further enhanced by the incorporating TiO2 P90 nanofiller in the electrolyte. The best solid-state solar cell showed a significantly higher efficiency of 4.41 % with a short-circuit current density of 8.41 mA cm−2, open-circuit voltage of 748.3 mV and a high fill factor of 70.16 % under the simulated light of 100 mW cm−2 with AM 1.5 filter. This is the first report describing the efficiency enhancement in a solid-state dye sensitized solar cell based on a solid polymer electrolyte incorporating a binary cation iodide salt and TiO2 nanofiller and a photoanode co-sensitized with PbS/CdS quantum dots and N719 dye demonstrating the cumulative effect by the mixed cation effect and co-sensitization.



中文翻译:

固态太阳能电池与PbS / CdS量子点和N719染料共敏化,并基于具有二元阳离子和纳米填料的固体聚合物电解质

由于能量转换过程能够吸收来自广泛范围的太阳光谱(包括可见光和近红外区域)的光子,因此能量转换过程使共增感型太阳能电池受到更多关注。TiO 2电极与PbS / CdS核-壳量子点和N719染料共敏化。PbS / CdS / N719染料敏化太阳能电池是用基于聚(环氧乙烷)的固态聚合物电解质制成的,该电解质由碘化物/三碘化物氧化还原对组成。通过加入不同尺寸阳离子的二碘盐混合物,碘化四丙铵和碘化钾,可以提高电解质的碘离子传导率。通过掺入TiO 2进一步提高了太阳能电池的性能电解质中的P90纳米填料。最好的固态太阳能电池在模拟光为100的情况下,其短路电流密度为8.41 mA cm -2,开路电压为748.3 mV,填充系数为70.16%,显示出显着更高的效率,为4.41%。配备AM 1.5滤镜的mW cm -2。这是第一个描述固态染料敏化太阳能电池效率提高的报告,该太阳能电池基于固体聚合物电解质,该电解质包含二元碘化盐和TiO 2纳米填料以及与PbS / CdS量子点和N719染料共敏化的光阳极通过混合阳离子效应和共敏化产生累积效应。

更新日期:2020-09-26
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