Journal of Organometallic Chemistry ( IF 2.3 ) Pub Date : 2020-09-19 , DOI: 10.1016/j.jorganchem.2020.121538 Diana Elizabeth Jose , U S Kanchana , Thomas V Mathew , Gopinathan Anilkumar
Under increasing environmental awareness and with the increasing interest in green chemistry processing, Suzuki-Miyaura coupling reaction can be proceeded using phase transfer catalyst (PTC), instead of using toxic ligands and organic solvents is a great stride in synthetic organic chemistry. The phase transfer catalyst allows transferring substance from one system to another in a chemical reaction between the two non-miscible, heterogeneous systems, which itself has both functional sites to get solubilized in both system. This review highlights the use of various PTC's, and the importance for the reaction outcome and applicability in Suzuki-Miyaura coupling reaction from 2009 to 2020.
中文翻译:
相转移催化剂在铃木宫浦交叉偶联反应中的最新研究
在日益增长的环境意识和对绿色化学处理的兴趣日益增长的情况下,可以使用相转移催化剂(PTC)进行铃木-宫浦偶联反应,而不是使用有毒的配体和有机溶剂,这在合成有机化学中取得了巨大进步。相转移催化剂允许在两个不可混溶的非均相系统之间的化学反应中将物质从一个系统转移到另一个系统,该系统本身具有两个要在两个系统中溶解的功能性位点。这篇综述着重介绍了各种PTC的使用,以及对于2009年至2020年Suzuki-Miyaura偶联反应的反应结果和适用性的重要性。