Abstract

We review the synthesis methods, crystal parameters, and band structure of two-dimensional and quasi-two-dimensional materials, including graphene; group IV‒VIII transition metal dichalcogenides; 2D binary chalcogenides \({{{\text{A}}}^{{{\text{IV}}}}}{{{\text{B}}}^{{{\text{VI}}}}}\), \({\text{A}}_{m}^{{{\text{IV}}}}{\text{B}}_{n}^{{{\text{VI}}}}\), \({{{\text{A}}}^{{{\text{III}}}}}{{{\text{B}}}^{{{\text{VI}}}}}\), \({\text{A}}_{m}^{{{\text{III}}}}{\text{B}}_{n}^{{{\text{VI}}}}\), and \({{{\text{A}}}^{{{\text{II}}}}}{{{\text{B}}}^{{{\text{VI}}}}}\) of group IV, III, and II transition metals; Ti, Zr, Hf, Bi, and Sb trichalcogenides; \({{{\text{A}}}^{{\text{V}}}}{{{\text{B}}}^{{\text{V}}}}\) (AsN, AsP, PN, SbAs, SbN, SbP) 2D materials; \({{{\text{A}}}^{{{\text{III}}}}}{\text{N}}\) (A = Al, Ga, In, B) 2D nitrides; monoatomic 2D materials (phosphorene P, plumbene Pb, stanene Sn, germanene Ge, silicene Si, antimonene Sb, arsenene As, bismuthene Bi, borophene B, and octo-nitrogene 8‑N); functionalized graphene and silicon carbide SiC; CO, GeO, and SnO 2D oxides; 2D transitional metal dioxides, Ge, and Sn; 2D trioxides MoO₃ and WO₃; and transition metal di- and trihalides.

中文翻译：

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基于二维材料的光电子和纳米电子学。第一部分：二维材料：特性和合成

摘要

我们综述了包括石墨烯在内的二维和准二维材料的合成方法，晶体参数和能带结构。IV‒VIII族过渡金属二卤化物；二维二进制硫族化物\（{{{\ text {A}}} ^ {{{\ text {IV}}}}} {{{\ text {B}}} ^ {{{\ text {VI}}}}} } \），\（{\ text {A}} _ {m} ^ {{{\ text {IV}}}} {\ text {B}} _ {n} ^ {{{\ text {VI}} }} \），\（{{{\ text {A}}} ^ {{{\ text {III}}}}} {{{\ text {B}}} ^ {{{\ text {VI}} }}} \），\（{\ text {A}} _ {m} ^ {{{\ text {III}}}}} {\ text {B}} _ {n} ^ {{\ text {VI }}}} \）和\（{{{\ text {A}}} ^ {{{\ text {II}}}}} {{{\ text {B}}} ^ {{{\ text { VI}}}}} \） IV族，III和II的过渡金属; Ti，Zr，Hf，Bi和Sb三卤化钨; \（{{{\ text {A}}} ^ {{\ text {V}}}} {{{\ text {B}}} ^ {{\ text {V}}}} \} \）（AsN，AsP，PN，SbAs，SbN，SbP）2D材料; \（{{{\ text {A}}} ^ {{{\ text {III}}}}} {\ text {N}} \）（A = Al，Ga，In，B）2D氮化物；单原子二维材料（磷P，铅Pb，锡Sn，锗烯Ge，硅Si，锑Sb，砷As，铋Bi，硼苯硼B和辛基氮8-N）；功能化石墨烯和碳化硅SiC; CO，GeO和SnO 2D氧化物；2D过渡金属氧化物Ge和Sn；2D三氧化物MoO ₃和WO ₃ ; 过渡金属二卤化物和三卤化物。