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New transformations of phosphorylthioformic acid morpholides
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-08-01 , DOI: 10.1007/s11172-020-2943-z M. A. Kozlov , Y. A. Volkova , I. V. Zavarzin
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-08-01 , DOI: 10.1007/s11172-020-2943-z M. A. Kozlov , Y. A. Volkova , I. V. Zavarzin
Phosphorylthioformic acid morpholides can be successfully used as a precursor in the synthesis of complexes of phosphoryl-substituted thiohydrazides with hydrazine and morpholine. The reaction of sterically hindered phosphorylthioformic acid morpholides with hydrazine hydrate proceeds chemoselectively with the formation of hydrazono(morpholino)methylphosphodiamides.
中文翻译:
磷酰硫甲酸吗啉的新转化
磷酰硫代甲酸吗啉可成功用作合成磷酰取代的硫代酰肼与肼和吗啉的复合物的前体。位阻磷酰硫甲酸吗啉与水合肼的反应化学选择性地进行,形成腙(吗啉)甲基磷二酰胺。
更新日期:2020-08-01
中文翻译:
磷酰硫甲酸吗啉的新转化
磷酰硫代甲酸吗啉可成功用作合成磷酰取代的硫代酰肼与肼和吗啉的复合物的前体。位阻磷酰硫甲酸吗啉与水合肼的反应化学选择性地进行,形成腙(吗啉)甲基磷二酰胺。