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Packing fraction, bond valence and crystal structure of AVO 4 (A = Eu, Y) microwave dielectric ceramics with low permittivity
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-09-18 , DOI: 10.1007/s10854-020-04454-9
Jinwu Chen , Liang Fang , Jie Li , Ying Tang , Kai Cheng , Yijie Cao

The A3+B5+O4 binary oxides have a variety of different structures—monoclinic, and tetragonal—making them suitable candidates for laser hosts, energy storage, microwave dielectric substrates, etc. In this work, we prepared two tetragonal AVO4 (A = Eu, Y) ceramics with zircon structure. The powder X-ray diffraction (XRD) has been used to study phase purity of the zircon-type AVO4 (A = Eu, Y) ceramics. There was a significant correlation between microwave dielectric properties and relative density. Dense EuVO4 and YVO4 ceramics sintered at 1180 °C and 1240 °C exhibited promising microwave dielectric properties with εr = 11.6 and 9.9, Q × f = 46,862 GHz and 56,174 GHz, τf = − 49.6 ppm/°C and − 43.7 ppm/°C, respectively. In addition, the relationship between microwave dielectric properties and crystal structure of AVO4 (A = Eu, Y) ceramics were discussed by packing fraction and bond valence theory in detail.



中文翻译:

低介电常数的AVO 4(A = Eu,Y)微波介电陶瓷的填充率,结合价和晶体结构

A 3+ B 5+ O 4二元氧化物具有多种不同的结构(单斜晶和四方晶),使其适合用于激光主体,储能,微波介电基板等。在这项工作中,我们制备了两种四方晶AVO 4(A = Eu,Y)具有锆石结构的陶瓷。粉末X射线衍射(XRD)已用于研究锆石型AVO 4(A = Eu,Y)陶瓷的相纯度。微波介电特性和相对密度之间存在显着的相关性。密EuVO 4和YVO 4个陶瓷在1180烧结℃下和1240℃下表现出有希望的用微波介电性能ε - [R = 11.6和9.9,Q  ×  ˚F  = 46862 GHz和56174千兆赫,τ ˚F  43.7 PPM /℃, - = - 49.6 PPM /℃并。此外,通过堆积分数和键合价理论详细讨论了AVO 4(A = Eu,Y)陶瓷的微波介电性能与晶体结构之间的关系。

更新日期:2020-09-20
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