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Inside Back Cover
Chinese Journal of Chemistry ( IF 5.4 ) Pub Date : 2020-09-17 , DOI: 10.1002/cjoc.202090106


The inside back cover picture shows the controllable skeleton rearrangement of 3‐substituted cyclobutanones under basic conditions. In this paper, a series of 3‐substituted cyclobutanones with different Z group underwent skeleton rearrangement with the treatment of K3PO4 and 18‐crown‐6 ether. Various lactones, lactams and acids were afforded in this concise reaction. More interestingly, an eight‐membered ring was produced with pentaflurophenyl group as a good leaving group. More details are discussed in the article by Lu et al. on page 1103—1106.
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中文翻译:

内封底

封底的内部图片显示了在基本条件下3取代的环丁酮的可控骨架重排。本文用K 3 PO 4和18-crown-6醚处理了一系列带有不同Z基团的3-取代的环丁酮,进行了骨架重排。在该简洁的反应中提供了各种内酯,内酰胺和酸。更有趣的是,产生了一个带有五氟苯基作为良好离去基团的八元环。Lu等人的文章中讨论了更多细节。在第1103-1106页。
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更新日期:2020-09-18
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