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Intramolecular Dehydrogenative Coupling Approach to 2‐Oxindoles Using Fe(OAc)2/NaI/Na2S2O8
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-09-17 , DOI: 10.1002/ejoc.202001111
Junyan Zhao 1 , Xun Song 1 , Dong Li 1 , Jinfeng Zhao 2 , Jingping Qu 2 , Yuhan Zhou 1
Affiliation  

A novel method for the synthesis of 2‐oxindoles from 1,3‐dicarbonyl compounds based on ferrous salt and iodide catalyst was described. Through a new catalytic oxidation system, the intramolecular dehydrogenation coupling reaction was completed by using catalytic amount of iodine.
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中文翻译:

Fe(OAc)2 / NaI / Na2S2O8分子内脱氢偶联法制备2-辛醇

描述了一种基于亚铁盐和碘化物催化剂由1,3-二羰基化合物合成2-吲哚的新方法。通过新的催化氧化体系,利用催化量的碘完成了分子内脱氢偶联反应。
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更新日期:2020-10-29
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