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The effect of iron on the sound velocities of δ-AlOOH up to 135 GPa
Geoscience Frontiers ( IF 8.9 ) Pub Date : 2020-09-17 , DOI: 10.1016/j.gsf.2020.08.012
Xiaowan Su , Chaoshuai Zhao , Chaojia Lv , Yukai Zhuang , Nilesh Salke , Liangxu Xu , Hu Tang , Huiyang Gou , Xiaohui Yu , Qiang Sun , Jin Liu

δ-(Al,Fe)OOH is considered to be one of the most important hydrous phases on Earth, remaining stable under the extreme conditions throughout the mantle. The behavior of δ-(Al,Fe)OOH at high pressure is essential to understanding the deep water cycle. δ-(Al0.95Fe0.05)OOH crystals synthesized at 21 GPa and 1473 K were investigated by high-pressure Brillouin light scattering spectroscopy and synchrotron X-ray diffraction up to 135.4 GPa in diamond anvil cells. The incorporation of 5 mol% FeOOH increases the unit-cell volume of δ-AlOOH by ∼1% and decreases the shear-wave velocity (VS) by ∼5% at 20–135 GPa. In particular, the compressional (VP) and shear (VS) wave velocities of δ-(Al0.95Fe0.05)OOH are 7%–16% and 10%–24% greater than all the major minerals in the mantle transition zone including wadsleyite, ringwoodite, and majorite. The distinctly high sound velocities of δ-(Al0.95Fe0.05)OOH at 20–25 GPa may contribute to the seismic anomalies observed at ∼560–680 km depths in the cold and stagnant slab beneath Izu-Bonin and/or Korea. Furthermore, the VS of δ-(Al0.95Fe0.05)OOH is about 10% and 4%−12% lower than iron-bearing bridgmanite Mg0.96Fe0.05Si0.99O3 and ferropericlase (Mg0.92Fe0.08)O, respectively, under the lowermost mantle conditions, which might partially contribute to the large low-shear-velocity provinces and ultralow velocity zones at the bottom of the lower mantle.



中文翻译:

铁对高达135 GPa的δ-AlOOH声速的影响

δ-(Al,Fe)OOH被认为是地球上最重要的含水相之一,在整个地幔的极端条件下仍保持稳定。δ-(Al,Fe)OOH在高压下的行为对于理解深水循环至关重要。通过高压布里渊光散射光谱和高达135.4 GPa的同步辐射X射线衍射研究了在21 GPa和1473 K下合成的δ-(Al 0.95 Fe 0.05)OOH晶体。在20–135 GPa时,掺入5 mol%的FeOOH会使δ-AlOOH的晶胞体积增加约1%,并使剪切波速度(V S)降低约5%。特别是压缩力(V P)和剪切力(V S)δ-(Al 0.95 Fe 0.05)OOH的波速比地幔过渡带中的所有主要矿物(包括瓦兹利石,林木和主要矿物)高7%–16%和10%–24%。δ-(Al 0.95 Fe 0.05)OOH在20–25 GPa处明显较高的声速,可能有助于在伊豆邦宁和/或韩国下方的冷,停滞平板中约560至680 km的深度处观察到地震异常。此外,δ-(Al 0.95 Fe 0.05)OOH的V S比含铁的水辉锰矿Mg 0.96 Fe 0.05 Si 0.99 O 3和亚铁镁锰矿(Mg 0.92)低约10%和4%-12%在最低地幔条件下分别为Fe 0.08)O,这可能部分有助于下部地幔底部的大型低剪切速度省和超低速带。

更新日期:2020-09-18
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