Using wet impregnation method, MoO₃ particles were loaded on hierarchical silica support, SBA-15, and applied for oxidative desulfurization (ODS) process from a model oil containing dibenzothiophene (DBT). The experiments were carried out by the use of H₂O₂ and acetonitrile as oxidant and extractant. The MoO₃/SBA-15 catalyst was characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), field emission scanning electron microscope (FE-SEM) and Brunauer–Emmett–Teller (BET) analyses. At first, the effect of molybdenum loading was examined. Then, the effect of operating parameters on ODS including temperature, catalyst dosage, the molar ratio of H₂O₂/DBT and reaction time were investigated using Box–Behnken experimental design. The complete efficiency, ~ 100% S removal, was achieved by 0.004 g mL⁻¹ catalyst at 55 ºC within 49 min reaction time and H₂O₂/DBT = 9. At the optimized operating conditions, real oil cuts of gasoline and gas oil were tested and the S removal efficiency of 69.73% and 49% was achieved. The desulfurization activity of the catalyst from DBT model oil after 5 times regeneration was above 93%.

使用湿浸渍法，将MoO ₃颗粒负载在分级二氧化硅载体SBA-15上，并从含二苯并噻吩（DBT）的模型油中进行氧化脱硫（ODS）工艺。通过使用H ₂ O ₂和乙腈作为氧化剂和萃取剂进行实验。MoO ₃ / SBA-15催化剂通过粉末X射线衍射（XRD），傅立叶变换红外光谱（FTIR），能量色散X射线光谱（EDX），场发射扫描电子显微镜（FE-SEM）和Brunauer进行表征–Emmett-Teller（BET）分析。首先，研究了钼负载的影响。然后，操作参数对ODS的影响包括温度，催化剂用量，H的摩尔比使用Box–Behnken实验设计研究了₂ O ₂ / DBT和反应时间。完整的效率，〜100％S的去除，是通过实现0.004克毫升^{- 1}催化剂在55ºC内49分钟的反应时间和H ₂ ö ₂ / DBT = 9.在优化操作条件下，汽油和气体的实际油馏分对油进行了测试，脱硫效率分别为69.73％和49％。5次再生后，DBT模型油催化剂的脱硫活性高于93％。