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MoS 2 self-embedded in pleated carbon pyrolyzed by ionic liquids as a high-performance anode materials for lithium-/sodium-ion batteries
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-09-17 , DOI: 10.1007/s10854-020-04369-5
Hongshuai Zhang , Yanshuang Meng , Qianru Hu , Guixiang Zhao , Fuliang Zhu , Yue Zhang

MoS2 is a promising anode with high theoretical capacity in lithium-/sodium-ion batteries. Nevertheless, the unstable structure and poor conductivity of MoS2 limit its practical applications. Herein, a carbon layer-coated MoS2 composite (MoS2/C) is synthesized by a pyrolysis strategy, in which ionic liquid-derived carbon improves the conductivity and structural stability of composites by wrapping MoS2. When MoS2/C composite is used as anode in lithium-/sodium-ion batteries, it exhibits excellent stability, high capacity and long cycle life. After 50 cycles at 100 mA g−1, the lithium storage capacity of the MoS2/C composite is more than 760 mAh g−1, and the sodium storage capacity reaches 480 mAh g−1. When the current density is 2 A g−1, the sodium storage capacity maintains at 355 mAh g−1 after 500 cycles. Even after 1000 cycles, it still exhibits a stable lithium storage capacity of 350 mAh g−1 at the current density of 4 A g−1. The improved performance of MoS2/C composite can be explained by its stable structure and high charge mobility.



中文翻译:

MoS 2自嵌入在离子液体热解的褶皱碳中,作为锂/钠离子电池的高性能负极材料

MoS 2是锂/钠离子电池中具有高理论容量的有前途的阳极。然而,MoS 2的不稳定结构和差的电导率限制了其实际应用。本文中,通过热解策略合成了涂覆有碳层的MoS 2复合材料(MoS 2 / C),其中离子液体衍生的碳通过包裹MoS 2改善了复合材料的导电性和结构稳定性。当MoS 2 / C复合材料用作锂/钠离子电池的负极时,它具有出色的稳定性,高容量和长循环寿命。在100 mA g -1下循环50次后,MoS 2的锂存储容量/ C复合材料大于760 mAh g -1,钠存储容量达到480 mAh g -1。当电流密度为2 A g -1时,经过500次循环后,钠存储容量保持在355 mAh g -1。即使经过1000次循环,它在4 A g -1的电流密度下仍显示出350 mAh g -1的稳定锂存储容量。MoS 2 / C复合材料的性能改善可以用其稳定的结构和高的电荷迁移率来解释。

更新日期:2020-09-18
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