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Efficient photocatalytic mineralization of polymethylmethacrylate and polystyrene nanoplastics by TiO 2 /β-SiC alveolar foams
Environmental Chemistry Letters ( IF 15.7 ) Pub Date : 2020-09-17 , DOI: 10.1007/s10311-020-01099-2
Paul Henri Allé , Patricia Garcia-Muñoz , Kopoin Adouby , Nicolas Keller , Didier Robert

Household wastewaters contain microplastics and nanoplastics that end up in ecosystems because these pollutants are not filtered by current wastewater treatment plants. Therefore, there is a need for advanced removal technologies. Here, we tested the degradation of polymethylmethacrylate (PMMA) and polystyrene (PS) nanoparticles by photocatalysis with TiO2–P25/β-SiC foams under UV-A radiation. We studied the effect of flow rate, initial pH and light intensity. Results show that about 50% of the carbon of polymethylmethacrylate nanobeads are degraded in 7 h at an irradiance of 112 W/m2, a flow rate of 10 mL/min and an initial pH of 6.3. Degradation is faster at low pH (4–6) and low flow rate. 140-nm polystyrene degrades faster than 508-nm polystyrene.



中文翻译:

TiO 2 /β-SiC肺泡泡沫对聚甲基丙烯酸甲酯和聚苯乙烯纳米塑料的有效光催化矿化

家用废水中含有最终在生态系统中的微塑料和纳米塑料,因为这些污染物尚未被当前的废水处理厂过滤。因此,需要先进的去除技术。在这里,我们测试了TiO 2 –P25 /β-SiC泡沫在UV-A辐射下的光催化降解聚甲基丙烯酸甲酯(PMMA)和聚苯乙烯(PS)纳米颗粒的能力。我们研究了流速,初始pH和光强度的影响。结果显示,在112 W / m 2的辐射,10 mL / min的流速和6.3的初始pH值下,聚甲基丙烯酸甲酯纳米珠的碳在约7小时内降解了约50%。在低pH(4–6)和低流速下降解速度更快。140纳米聚苯乙烯的降解速度比508纳米聚苯乙烯的降解速度更快。

更新日期:2020-09-18
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