Direct carbonylation of the C–H bond is a great tool for installing a carbonyl group in a wide variety of substrates. This review summarizes the C–H bond carbonylation methodologies using the cobalt-catalyzed C–H bond functionalization approach. Despite the fact that cobalt-catalyzed carbonylation methodologies have been known since Murahashi's report in 1955, this area is still underdeveloped, particularly carbonylation of the C(sp³)–H bond.

中文翻译：

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钴催化的 CH 键羰基化。

C-H 键的直接羰基化是在各种底物中安装羰基的好工具。本综述总结了使用钴催化的 C-H 键官能化方法的 C-H 键羰基化方法。尽管自 1955 年 Murahashi 的报告以来，钴催化的羰基化方法已为人所知，但该领域仍不发达，特别是 C(sp ³ )-H 键的羰基化。