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The Application of Covalent Organic Frameworks for Chiral Chemistry.
Macromolecular Rapid Communications ( IF 4.6 ) Pub Date : 2020-09-16 , DOI: 10.1002/marc.202000404
Siqi Zhuo 1, 2 , Xiaoyue Zhang 1, 2 , Huan Luo 1, 2 , Xuehua Wang 1, 2 , Yibing Ji 1, 2
Affiliation  

Covalent organic frameworks (COFs) made their debut in 2005 and caused enthusiastic attention because of their ordered, crystalline structure. They are constructed with pure organic building blocks that are linked together by robust covalent linkages. COFs are applied in numerous fields due to their large surface area, architecture and chemistry stabilities, functional pore walls, and tunable frameworks. Incorporating COFs with chiral compounds can build chiral COFs (CCOFs), which have exhibited significant advantages in the chiral chemistry field. This review focuses on the applications of COFs for chiral catalysis, chiral separation, and chiral sensoring up to now. Furthermore, the synthesis and design strategies of CCOFs are also discussed in this article, since the COFs used in chiral chemistry are generally CCOFs. There also sums up the benefits and defects of COFs used in the chiral field and outlines future opportunities. The studies described in this review demonstrate not only the advantages of COFs in practical use but also novel solutions for the problems in the chirality area.

中文翻译:

共价有机骨架在手性化学中的应用。

共价有机骨架(COF)于2005年首次亮相,由于其有序的晶体结构而引起了热烈的关注。它们由通过牢固的共价键连接在一起的纯有机结构单元构建。由于它们的大表面积,结构和化学稳定性,功能性孔壁和可调框架,COF被应用于许多领域。将COF与手性化合物结合可以构建手性COF(CCOF),在手性化学领域已显示出显着优势。这篇综述着眼于COFs在手性催化,手性分离和手性传感方面的应用。此外,本文还讨论了CCOF的合成和设计策略,因为手性化学中使用的COF通常是CCOF。还总结了在手性领域中使用COF的利弊,并概述了未来的机会。这篇综述中描述的研究不仅证明了COF在实际使用中的优势,而且还针对手性领域的问题提供了新颖的解决方案。
更新日期:2020-10-19
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