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Ultra-low thermal conductivity and high thermoelectric performance realized in a Cu3SbSe4 based system
Materials Chemistry Frontiers ( IF 7 ) Pub Date : 2020-09-15 , DOI: 10.1039/d0qm00553c
J. M. Li 1, 2, 3, 4, 5 , H. W. Ming 1, 2, 3, 4, 5 , B. L. Zhang 1, 2, 3, 4, 5 , C. J. Song 1, 2, 3, 4, 5 , L. Wang 1, 2, 3, 4, 5 , H. X. Xin 1, 2, 3, 4, 5 , J. Zhang 1, 2, 3, 4, 5 , X. Y. Qin 1, 2, 3, 4, 5 , D. Li 1, 2, 3, 4, 5
Affiliation  

Cu3SbSe4-Based materials were fabricated through Sn-doping and AgSb0.98Ge0.02Se2 incorporation and their thermoelectric properties were investigated in the temperature range from 300 K to 675 K. A remarkable enhancement in thermoelectric performance was obtained, which can be ascribed to the synergistic adjustment of electrical and thermal transport. The introduction of AgSb0.98Ge0.02Se2 nanoparticles strengthened phonon scattering in the composites, resulting in a low thermal conductivity. Simultaneously, a high power factor was maintained. As a result, a maximum figure of merit of 1.23 was obtained at 675 K for the sample Cu3Sb0.96Sn0.04Se4–3 wt% AgSb0.98Ge0.02Se2, which is one of the highest values ever reported in the Cu3SbSe4-based system.

中文翻译:

在基于Cu3SbSe4的系统中实现超低导热率和高热电性能

通过Sn掺杂和AgSb 0.98 Ge 0.02 Se 2的掺入制备了Cu 3 SbSe 4基材料,并在300 K至675 K的温度范围内研究了它们的热电性能。热电性能得到了显着提高,可以达到归因于电力和热力运输的协同调整。AgSb 0.98 Ge 0.02 Se 2纳米颗粒的引入增强了复合材料中的声子散射,导致导热系数低。同时,维持了高功率因数。结果,样品铜在675 K下获得的最大品质因数为1.233 Sb 0.96 Sn 0.04 Se 4 -3 wt%AgSb 0.98 Ge 0.02 Se 2,这是基于Cu 3 SbSe 4的体系中报道的最高值之​​一。
更新日期:2020-11-03
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