当前位置: X-MOL 学术J. Hazard. Mater. › 论文详情
Fenton-type process using peracetic acid: efficiency, reaction elucidations and ecotoxicity
Journal of Hazardous Materials ( IF 9.038 ) Pub Date : 2020-09-15 , DOI: 10.1016/j.jhazmat.2020.123949
Thayrine Dias Carlos; Leydiane Barbosa Bezerra; Mayane Marques Vieira; Renato Almeida Sarmento; Douglas Henrique Pereira; Grasiele Soares Cavallini

Recent studies on Fenton-type processes involving peracetic acid (PAA) stimulated further development of advanced oxidative processes (AOPs). The objective of this work was to provide new information about such processes, elucidate their reaction mechanisms both experimentally and theoretically, and verify their possible uses. The Fenton-type reaction of PAA with Fe3+ exhibited a greater dye degradation efficiency than the Fenton process, while the efficiency of the PAA reaction with Fe2+ was very close of Fenton process. Moreover, the processes photocatalyzed by solar radiation demonstrated comparable efficiencies due to the photoreduction of Fe3+ to Fe2+. By conducting theoretical calculations, it was found that the formation of oxidizing radicals during the reaction of PAA with Fe2+ was not thermodynamically favorable and, therefore, unsuitable for practical use. In contrast, the processes occurred in the PAA/Fe3+ system included thermodynamically spontaneous reactions that generated peroxyl (CH3C(O)OO•), alkoxyl (CH3C(O)•), and hydroperoxyl (HO2•) radicals. The ecotoxicological tests demonstrated that the toxicity of the PAA to the organism Dugesia tigrina can be attributed to the presence of H2O2.

更新日期:2020-09-15

 

全部期刊列表>>
物理学研究前沿热点精选期刊推荐
chemistry
《自然》编辑与您分享如何成为优质审稿人-信息流
欢迎报名注册2020量子在线大会
化学领域亟待解决的问题
材料学研究精选新
GIANT
自然职场线上招聘会
ACS ES&T Engineering
科研绘图
ACS ES&T Water
ACS Publications填问卷
屿渡论文,编辑服务
阿拉丁试剂right
张晓晨
田蕾蕾
李闯创
刘天飞
隐藏1h前已浏览文章
课题组网站
新版X-MOL期刊搜索和高级搜索功能介绍
ACS材料视界
天合科研
x-mol收录
X-MOL
苏州大学
廖矿标
深圳湾
试剂库存
down
wechat
bug