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Recent developments and future perspectives of anionic batteries
Journal of Power Sources ( IF 9.2 ) Pub Date : 2020-09-13 , DOI: 10.1016/j.jpowsour.2020.228877
Guruprakash Karkera , M. Anji Reddy , Maximilian Fichtner

This paper contains a review of developments in anionic batteries. Among the several battery chemistries, Li-ion batteries (LIBs) have excelled in the past two decades. However, new cation based rechargeable battery chemistries of Na+, K+, Mg2+, Ca2+ shuttle have gained interest. Apart from cations, anionic shuttle dependent batteries offer great potential, too. While nickel metal hydride (Ni-MH) and nickel cadmium (Ni-Cd) batteries rely on OH ion shuttle and are well-studied, commercial anionic batteries, the new members to this family are fluoride-ion batteries (FIBs) and chloride-ion batteries (CIBs). These batteries utilize metal and metal fluoride or metal chloride containing electrodes as source and target of the shuttle ion. The new generation of fluoride-ion, chloride-ion batteries can theoretically offer higher energy densities than LIBs. Herein, we discuss the origin, developments of CIBs, FIBs, and the advancements achieved so far on various electrolytes, cathodes, and anode materials. We will also briefly discuss the status of related aluminium chloride-based, Ni-MH, and Ni-Cd batteries. Overall, this review investigates the progression, state of the art, trends in outcomes, and provides future perspectives, with an anticipating trajectory towards its practical applications.



中文翻译:

阴离子电池的最新发展和未来展望

本文对阴离子电池的发展进行了回顾。在几种电池化学中,锂离子电池(LIB)在过去的二十年中表现出色。然而,Na +,K +,Mg 2 +,Ca 2+穿梭的新型基于阳离子的可再充电电池化学方法引起了人们的兴趣。除阳离子外,与阴离子穿梭相关的电池也具有巨大的潜力。而镍金属氢化物(Ni-MH),镍镉(Ni-Cd)电池,依靠OH -离子梭和经过深入研究的商用阴离子电池,该家族的新成员是氟离子电池(FIB)和氯离子电池(CIB)。这些电池利用含金属和金属氟化物或含金属氯化物的电极作为穿梭离子的源和靶。理论上,新一代的氟离子,氯离子电池可提供比锂电池更高的能量密度。在本文中,我们讨论了CIB,FIB的起源,发展以及迄今为止在各种电解质,阴极和阳极材料上取得的进展。我们还将简要讨论相关的氯化铝基,Ni-MH和Ni-Cd电池的状态。总的来说,这篇综述调查了进展,技术水平,结果趋势,并提供了未来的展望,并展望了其实际应用的轨迹。

更新日期:2020-09-14
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