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Quartz-enhanced photoacoustic spectroscopic methane sensor system using a quartz tuning fork-embedded, double-pass and off-beam configuration
Photoacoustics ( IF 7.9 ) Pub Date : 2020-03-10 , DOI: 10.1016/j.pacs.2020.100174
Lien Hu , Chuantao Zheng , Minghui Zhang , Dan Yao , Jie Zheng , Yu Zhang , Yiding Wang , Frank K. Tittel

Development of a methane (CH4) sensor system was reported based on a novel quartz-tuning-fork (QTF)-embedded, double-pass, off-beam quartz-enhanced photoacoustic spectroscopy (DP-OB-QEPAS). A simplified and accurate numerical model was presented to optimize the DP-OB-QEPAS spectrophone and to enhance the detection sensitivity. A compact and fiber-coupled acoustic detection module (ADM) with a volume of 3 × 2×1 cm3 and a weight of 9.7 g was fabricated. A continuous-wave distributed feedback diode laser was used to target the CH4 absorption line at 6046.95 cm−1. With the combination of wavelength modulation spectroscopy (WMS) and second harmonic (2f) detection technique, the CH4 sensor system reveals a 1σ detection limit of 8.62 parts-per-million in volume (ppmv) for a 0.3 s averaging time with an optimized modulation depth of 0.26 cm−1. The proposed CH4 sensor shows a similar or even lower level in the normalized noise equivalent absorption coefficient (NNEA) (1.8 × 10−8 cm−1∙W/√Hz), compared to previously reported QEPAS-based CH4 sensors.



中文翻译:

石英增强型光声光谱甲烷传感器系统,采用嵌入式石英音叉,双通和近光束配置

据报道,甲烷(CH 4)传感器系统的开发基于一种新型的嵌入石英音叉(QTF),双通,离束的石英增强光声光谱法(DP-OB-QEPAS)。提出了一种简化而精确的数值模型,以优化DP-OB-QEPAS光谱仪并提高检测灵敏度。制作了体积为3×2×1 cm 3,重量为9.7 g的紧凑型纤维耦合声学检测模块(ADM)。使用连续波分布反馈二极管激光器将CH 4吸收线对准6046.95 cm -1。结合波长调制光谱(WMS)和二次谐波(2 f)检测技术,CH 4传感器系统在0.3 s的平均时间内显示出的1σ检测极限为8.62百万分之体积(ppmv),优化调制深度为0.26 cm -1。与先前报道的基于QEPAS的CH 4传感器相比,拟议的CH 4传感器在归一化噪声等效吸收系数(NNEA)(1.8×10 -8 cm -1 ∙W /√Hz)中显示出相似或更低的水平。

更新日期:2020-03-10
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