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Multi-pollutant air quality analyses and apportionment of sources in three particle size categories at Taj Mahal, Agra
Atmospheric Pollution Research ( IF 4.5 ) Pub Date : 2020-09-12 , DOI: 10.1016/j.apr.2020.09.001
Pavan K. Nagar , Prashant Gargava , Vijay K. Shukla , Mukesh Sharma , Ashutosh K. Pathak , Dhirendra Singh

Taj Mahal, an iconic monument at Agra, India, is faced with the high air pollution levels, affecting its facade. A study was undertaken at the Taj Mahal (June 7–26, 2018) to measure PM2.5, PM10, TSP and their chemical composition: metals, ions, elemental and organic carbons and molecular markers (polyaromatic hydrocarbons, n-alkanes, hopanes and sterols). The objectives of the study were to (i) assess the contribution of sources to PM2.5, PM10 and TSP by employing receptor modelling (USEPA's Chemical Mass Balance model 8.2) and (ii) measure levels of reactive (NH3, SO2, NO2), acidic (HCl, HNO3) and corrosive (H2S) gases.

The PM levels were: PM2.5 65 ± 13; PM10 234 ± 84 and TSP 465 ± 204 μg/m3. The percent mass of metals (32–39) was the maximum in all PM size categories followed by secondary inorganic aerosol (SIA; 6–21). PM2.5 had a substantial contribution to coal combustion and fly ash (35%), followed by vehicles (19%). The contribution of soil and road dust was maximum to PM10 (39%) and TSP (61%), followed by the contribution of coal and fly ash in PM10 (34%) and TSP (22%). The presence of HCl (9.44 ± 4.61 μg/m3) suggested the contribution of burning of coal, plastic, paper and waste. The other concern was levels of NH3 (30 ± 14 μg/m3), which adds to the formation of SIA. The major source of NH3 could be from the upstream discharges of partially treated sewage in the River Yamuna, flowing adjacent to the Taj Mahal.



中文翻译:

阿格拉泰姬玛哈陵的三种污染物的多污染物空气质量分析和源分配

泰姬陵是印度阿格拉的标志性古迹,面临着高空气污染水平,影响了其外墙。在泰姬陵(2018年6月7日至26日)进行了一项研究,以测量PM 2.5, PM 10,TSP及其化学成分:金属,离子,元素和有机碳以及分子标记(聚芳烃,正构烷烃,ane烷)和固醇)。该研究的目的是(i)通过采用受体模型(USEPA的化学物质平衡模型8.2 )评估源对PM 2.5, PM 10和TSP的贡献,以及(ii)测量反应性(NH 3,SO 2, NO 2),酸性(HCl,HNO 3)和腐蚀性(H 2S)气体。

PM水平为:PM 2.5 65±13;PM 10 234±84和TSP 465±204μg/ m 3。在所有PM尺寸类别中,金属的质量百分比(32-39)最大,其次是次要无机气溶胶(SIA; 6-21)。PM 2.5对燃煤和粉煤灰有重要贡献(35%),其次是车辆(19%)。土壤和道路灰尘对PM 10(39%)和TSP(61%)的贡献最大,其次是PM 10(34%)和TSP(22%)的煤和粉煤灰的贡献。HCl(9.44±4.61μg/ m 3)的存在表明煤,塑料,纸张和废物的燃烧。另一个问题是NH 3(30±14μg/ m3),这增加了SIA的形成。NH 3的主要来源可能是从Yamuna河中流向毗邻泰姬陵的部分污水的上游排放。

更新日期:2020-09-13
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