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Synthesis and evaluation of indole-substituted N-heterocyclic carbene ligands
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2020-09-12 , DOI: 10.1016/j.tetlet.2020.152450
Huan Yan , Zhongxian Liu , Kai Tan , Kai Tan , Ruigeng Ji , Yingxin Ye , Tingbing Yan , Yuehai Shen

Indole-substituted N-heterocyclic carbene ligands were synthesized and evaluated through both computational and experimental methods. The performances of medium-sized imidazolylidenes IIn3 and IIn4 were comparable to IPr in the Cu(I)-catalyzed carboxylation of organoboronic esters.



中文翻译:

吲哚取代的N-杂环卡宾配体的合成与评价

合成并通过计算和实验方法对吲哚取代的N-杂环卡宾配体进行了合成和评估。在Cu(I)催化的有机硼酸酯的羧化反应中,中等大小的咪唑基亚胺IIn3IIn4的性能与IPr相当。

更新日期:2020-10-12
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