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Development of New Synthetic Strategies, Tactics and their Applications
The Chemical Record ( IF 6.6 ) Pub Date : 2019-10-21 , DOI: 10.1002/tcr.201900041
Sambasivarao Kotha 1 , Milind Meshram 1
Affiliation  

This account covers our work related to the development of various synthetic methodologies since 1994. We summarized our strategies and their application to design various functional molecules. In this regard, we also report the utility of our methodologies in others research work. These methods we report here are simple and efficient for the synthesis of a wide variety of intricate molecules such as heterocycles, polycycles, unusual α‐amino acids, star‐shaped molecules, and modified peptides. For this purpose, we used various transition metal‐based reagents and catalysts. Various popular reactions such as metathesis, Suzuki coupling, [2+2+2] cyclotrimerization were used to assemble these targets. Moreover, rongalite has been used to expand the Diels‐Alder chemistry.

中文翻译:

新的合成策略,策略及其应用的发展

自1994年以来,该报告涵盖了我们与各种合成方法学发展相关的工作。我们总结了我们的策略及其在设计各种功能分子中的应用。在这方面,我们还报告了我们的方法论在其他研究工作中的效用。我们在这里报告的这些方法对于合成各种复杂的分子是简单而有效的,例如杂环,多环,不寻常的α-氨基酸,星形分子和修饰的肽。为此,我们使用了各种基于过渡金属的试剂和催化剂。各种流行的反应,例如复分解,Suzuki偶联,[2 + 2 + 2]环三聚被用来组装这些靶标。此外,使用了菱镁矿来扩展Diels-Alder化学。
更新日期:2019-10-21
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