Abstract

Published data on the electronic structures and magnetic behavior of the mononuclear cobalt and iron o-benzoquinone complexes with tetradentate nitrogen-containing bases are reviewed. The chosen objects are of significant interest due to their ability to manifest magnetic bistability, indicating wide prospects of the practical use of compounds of this class in molecular electronics and spintronics. The influence of structural features of the complexes on their magnetic properties is discussed on the basis of the quantum-chemical calculation results.

中文翻译：

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具有四齿N-供体基的单核钴和铁邻醌复合物：结构和性质

摘要

审查了有关具有四齿含氮碱的单核钴和邻邻苯二酚铁配合物的电子结构和磁行为的公开数据。选定的物体由于其表现出双稳态的磁性而备受关注，这表明这类化合物在分子电子学和自旋电子学中的实际应用前景广阔。根据量子化学计算结果，讨论了配合物的结构特征对其磁性能的影响。