The radical cation and dication salts of a tetrathiafulvalene (TTF) derivative functionalized with two amino groups have been successfully stabilized and isolated specifically by chemical oxidation using a polyfluoroalkoxyaluminate weak coordinating anion, [Al(OR_F)₄]⁻ (OR_F = OC(CF₃)₃). These compounds were characterized by UV-Vis-NIR absorption spectroscopy, ¹H NMR, EPR, and X-ray single crystal diffraction, respectively. Comprehensive research on their structure–property relationship in conjunction with theoretical calculations has been carried out.

中文翻译：

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稳定和分离氨基官能化的四硫富瓦烯衍生物的阳离子和阳离子盐

通过使用多氟烷氧基铝酸盐弱配位阴离子[Al（OR _F）₄ ] ^-（OR _F = OC（）的化学氧化，已成功地稳定并分离了被两个氨基官能化的四硫富瓦烯（TTF）衍生物的自由基阳离子和阳离子盐。CF ₃）₃）。这些化合物分别通过UV-Vis-NIR吸收光谱，¹ H NMR，EPR和X射线单晶衍射进行表征。结合理论计算，对它们的结构－性质关系进行了综合研究。