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Remote sp2 C–H Carboxylation via Catalytic 1,4-Ni Migration with CO2
Journal of the American Chemical Society ( IF 15.0 ) Pub Date : 2020-09-10 , DOI: 10.1021/jacs.0c08810
Marino Börjesson 1 , Daniel Janssen-Müller 1 , Basudev Sahoo 1 , Yaya Duan 1 , Xueqiang Wang 1 , Ruben Martin 1, 2
Affiliation  

A remote catalytic reductive sp2 C-H carboxylation of arenes with CO2 (1 bar) via 1,4-Ni migration is disclosed. This protocol constitutes the first catalytic 1,4-Ni migration reported to date, thus offering new vistas in the Ni-catalyzed reductive coupling arena while providing an unconventional new platform for incorporating electrophilic sites at remote sp2 C-H linkages.

中文翻译:

通过催化 1,4-Ni 迁移与 CO2 进行远程 sp2 C-H 羧化

公开了芳烃与CO 2 (1 bar)通过1,4-Ni迁移的远程催化还原sp 2 CH羧化。该协议构成了迄今为止报道的第一个催化 1,4-Ni 迁移,从而在 Ni 催化还原耦合领域提供了新的前景,同时提供了一个非常规的新平台,用于在远程 sp2 CH 连接处结合亲电子位点。
更新日期:2020-09-10
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