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One-pot facile synthesis of green-emitting fluorescent silicon quantum dots for the highly selective and sensitive detection of nitrite in food samples
Dyes and Pigments ( IF 4.5 ) Pub Date : 2020-09-11 , DOI: 10.1016/j.dyepig.2020.108848
Na Wei , Meng-Xia Wei , Bo-Hui Huang , Xiao-Feng Guo , Hong Wang

Owing to the outstanding properties, fluorescent silicon quantum dots (SiQDs) have attracted immense attention in recent years. In this work, the facile synthesized, environment friendly green-emitting SiQDs (g-SiQDs) were prepared for the detection of nitrite (NO2). It has excellent merits including excellent water-dispersible, photo-stability and salt tolerance. The fluorescence peak at 503 nm could be selectively quenched by NO2 due to the synergy of inner filter effect (IFE) and photo induced electron transfer (PET). There was a linear relationship between fluorescence quenching efficiency and the concentration of NO2 from 0.1 to 6.0 μM (R2 = 0.9969) with a limit of detection (LOD) of 25 nM, and the sensor displayed a significant selectivity toward NO2. Furthermore, the g-SiQDs were successfully applied to analysis NO2 in food samples after simple pretreatment with satisfactory recoveries, and our method has good potential for routine analyze of NO2 in food samples.



中文翻译:

一锅式合成绿色荧光荧光量子点,用于食品样品中亚硝酸盐的高选择性和灵敏检测

由于其优异的性能,荧光硅量子点(SiQD)近年来引起了极大的关注。在这项工作中,合成的容易,环境友好的绿色发光SiQDs(G-SiQDs)被用于检测亚硝酸盐的制备(NO 2 - )。它具有优异的优点,包括出色的水分散性,光稳定性和耐盐性。在503 nm处的荧光峰可以通过NO来选择性地淬灭2 -由于内过滤器效果(IFE)和光诱导电子转移(PET)的协同作用。有荧光猝灭效率和NO的浓度之间的线性关系2 - 0.1至6.0μM(R 2 = 0.9969)与25nM的检测限(LOD的限制),并且传感器所显示的显著选择性朝向NO 2 - 。此外,G-SiQDs成功地应用到分析NO 2 -食物样本中简单的预处理满意收回的金额后,我们的方法有很好的潜力对NO的常规分析2 -食品样品英寸

更新日期:2020-09-20
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