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Synthesis of New Lipophilic Cyclopentafullerenes from Long-Chain Alka-2,3-dienoates
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2020-09-10 , DOI: 10.1134/s1070428020070118
A. F. Mukhametyanova , I. M. Sakhautdinov , T. R. Nugumanov , Yu. N. Biglova

Abstract

Long-chain alka-2,3-dienoates were synthesized via the Wittig reaction from the corresponding fatty acids, and the subsequent triphenylphosphine-catalyzed [3+2]-cycloaddition to fullerene C60 afforded new lipophilic cyclopentafullerenes.



中文翻译:

从长链烷基2,3-二烯酸酯合成新的亲脂性环戊富勒烯

摘要

通过维蒂希反应,由相应的脂肪酸合成长链2,3-二烯酸长链烷基酯,随后将三苯膦催化的[3 + 2]-环加成至富勒烯C 60,得到新的亲脂性环戊富勒烯。

更新日期:2020-09-11
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