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Improving the polysulfide barrier by efficient carbon nanofibers coating on separator/cathode for Li-S batteries
Journal of Solid State Electrochemistry ( IF 2.5 ) Pub Date : 2020-07-10 , DOI: 10.1007/s10008-020-04749-1
Francisco J. García-Soriano , M. Laura Para , Guillermina L. Luque , Daniel Barraco , Ezequiel P. M. Leiva , German Lener

High-power high-density lithium rechargeable batteries are necessary to meet the energy demand of electric vehicles and high-power stationary grids. Here, we present a straightforward method for obtaining carbon nanofibers (CNFs) as a polysulfide barrier in Li-S cells, resulting in a significant increase in cell performance. CNFs were coated both on the separator and on the cathode. The CNF-coated cathode showed a specific capacity of 1010 mA h g−1 after 250 cycles at 0.2 C, with a capacity fading of 0.021% per cycle. In addition, at 1 C, it delivered 946 mA h g−1, thus presenting a fast Li+ transport with a good capacity. This result turns CNFs-coated cathodes into a promising system for obtaining high-performance Li-S cells.



中文翻译:

通过在Li-S电池的隔膜/阴极上有效地涂覆碳纳米纤维来改善多硫化物的阻挡层

为了满足电动汽车和大功率固定电网的能源需求,必须使用大功率高密度锂可充电电池。在这里,我们提出了一种简单的方法来获得碳纳米纤维(CNF)作为Li-S电池中的多硫化物阻挡层,从而显着提高电池性能。CNF既涂覆在隔板上,又涂覆在阴极上。经CNF涂覆的阴极在0.2 C下经过250次循环后显示出1010 mA h g -1的比容量,每循环0.021%的容量衰减。另外,在1 C时,它的传递能力为946 mA h g -1,因此呈现出具有良好容量的快速Li +传输。这一结果使涂有CNF的阴极成为获得高性能Li-S电池的有前途的系统。

更新日期:2020-09-11
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